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SCHOTT produces optical glass with 100% H2

After successfully testing glass production with 100% H2 on a laboratory scale last spring, the technology group SCHOTT has now completed the much anticipated industrial-scale application. For three days, the Mainz-based specialty glass expert melted optical glass in a furnace using the new technology for the first time – exclusively heated by H2, completely free of natural gas.

SCHOTT has been conducting its tests with gray H2 because green H2, produced from renewable energies, is not yet available in sufficient quantities. The large-scale test received excellent marks, and the quality of the glass is now being analyzed.

Successful testing on a large industrial scale: SCHOTT has produced an optical glass with 100% hydrogen. Photo: SCHOTT

"The test with 100% H2 is pioneering work for the specialty glass industry. If the tests show that the quality of the glass is also right and the glass properties remain unchanged, H2 would indeed be a suitable technology option," said SCHOTT project manager Dr. Lenka Deneke.

The test manager emphasizes that the experience gained from last year's tank tests with an initial 35% H2-by-volume tremendously helped with this success, but also asserts that there are still many unanswered questions requiring further research. For example: How does the use of H2 impact the complex melting processes, and therein, the quality of different products?  What long-term effects does heating with H2 have on the plant itself?  And what infrastructure needs to be adapted in order for H2 to be optimally used as a substitute for natural gas in operations?

To answer these questions, SCHOTT chose an optical glass as the first test product. The technology group manufactures over 100 types of optical glass from high-quality raw materials for various applications, such as consumer goods and measurement technology, as well as optical systems in research and development. The challenge is that the glass must have the highest homogeneity and transmission properties. This also applies to molten glass, which undergoes strict quality testing.

If the glass meets the high product requirements, it will be sent to the customer. "We would then have confirmation that the use of 100% H2 instead of fossil fuels delivers the same quality under industrial conditions," said Deneke. A permanent changeover would then also require further long-term tests and a continuous supply via a H2 pipeline. Only then would the group have taken another important step towards its strategic goal of climate-neutral glass production by 2030. In this context, climate-neutral means no Scope 1 or 2 emissions according to the Greenhouse Gas Protocol. SCHOTT is pursuing this goal with activities in four fields of action: Technology change (such as the switch to green H2), expansion of energy efficiency, conversion to 100% green electricity and, as a final step, the compensation of remaining emissions through involvement in climate protection projects.

SCHOTT has already achieved the switch to 100% green electricity, and energy efficiency is being continuously and systematically increased. The technology change is primarily about replacing natural gas for the operation of the furnaces. Either through electrification with green electricity or in future through the use of green H2. To this end, SCHOTT had already carried out the first large-scale tests with local partners towards the end of 2022 with 35% H2 added to natural gas, before laboratory tests with 100% H2 use followed in spring 2023, paving the way for large-scale industrial use.

For the large-scale tank test with 100% H2 heating, the H2 tank at SCHOTT in Mainz was filled three times – but with gray, not green, climate-neutral H2. This is because H2 produced using renewable energies is currently still in short supply. "We deliberately decided to use it so that we wouldn't lose any time testing its technical feasibility. This is sufficient for our tests, but we urgently need green energy for climate protection," said Dr Frank Heinricht, Chairman of the Board of Management at SCHOTT and responsible for the Group's sustainability strategy. The appeal to politicians: "Companies from energy-intensive industries need to set the course for the fastest possible development of a functioning infrastructure for green electricity and green H2 in Germany. Then our commitment will pay off, for the climate and for the competitiveness of our industry."

In addition to its own investments, SCHOTT receives financial support from various institutions for its developmental work in the field of H2. The tests were supported by the Federal Ministry of Education and Research BMBF and the DLR project management organization in the MiGWa project as well as "Financed by the European Union-NextGenerationEU".